Issue 16, 1976
From the journal:

Journal of the Chemical Society, Chemical Communications

Some η1 and η3-allylic and metallocyclobutane derivatives of molybdenum and tungsten

Michel Ephritikhine,   Malcolm L. H. Green  and  Robert E. MacKenzie  

Abstract

Nucleophilic attack by R–= H– or Me– on [W(η5-C5H5)2(η3-CH2CHCH2)]+PF6– occurs on the central carbon of the η3-allylic group giving the metallocyclobutane compounds [W(η5-C5H5)2(CH2CHRCH2)] which, for R[double bond, length half m-dash]H, undergo deuteriation giving [W(η5-C5H5)2H(CH2CHCH2D)]+PF6–; similar attack occurs on the analogous molybdenum compounds.

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Article information

DOI
https://doi.org/10.1039/C39760000619
Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 619-621

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Some η1 and η3-allylic and metallocyclobutane derivatives of molybdenum and tungsten

M. Ephritikhine, M. L. H. Green and R. E. MacKenzie, J. Chem. Soc., Chem. Commun., 1976, 619 DOI: 10.1039/C39760000619

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