Issue 16, 1976
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and electron spin resonance study of stable dialkyls and diamides of phosphorus and arsenic, R12M· and (R22N)2M·

Michael J. S. Gynane,   Andrew Hudson,   Michael F. Lappert  and  Philip P. Power  

Abstract

Photolysis of toluene solutions of dialkyl-phosphorus or -arsenic chlorides [(Me3Si)2CH]2MCl (M = P or As) or bisamido-phosphorus or -arsenic chlorides [(Me3Si)2N]2MCl (M = P or As) in the presence of an electron-rich olefin leads to solutions containing persistent (t½ > 1 month at 20 °C) two-co-ordinate phosphorus or arsenic-centred radicals [(Me3Si)2CH]2M· or [(Me3Si)2N]2M·(M = P or As) characterised by their e.s.r. spectra.

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Article information

DOI
https://doi.org/10.1039/C39760000623
Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 623-624

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Synthesis and electron spin resonance study of stable dialkyls and diamides of phosphorus and arsenic, R12M· and (R22N)2M·

M. J. S. Gynane, A. Hudson, M. F. Lappert and P. P. Power, J. Chem. Soc., Chem. Commun., 1976, 623 DOI: 10.1039/C39760000623

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