Issue 18, 1976

X-Ray structures of [Zn(S2CNMe2)3] and [Zn(C7H4NS2)3(OH2)], possible intermediates in zinc-assisted rubber vulcanisation

Abstract

Reaction of [Zn(S2CNMe2)2] or [Zn(C7H4NS2)2](C7H5NS2= 2-mercaptobenzothiazole) with stearic acid in the presence of R4NOH (R = Et or Bun) afforded [Et4N][Zn(S2CNMe2)3](I), and [Bun4N][Zn(C7H4NS2)3]·H2O (II), respectively, and the structures of (I) and (II) have been determined crystallographically.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 743-744

X-Ray structures of [Zn(S2CNMe2)3] and [Zn(C7H4NS2)3(OH2)], possible intermediates in zinc-assisted rubber vulcanisation

C. C. Ashworth, N. A. Bailey, M. Johnson, J. A. McCleverty, N. Morrison and B. Tabbiner, J. Chem. Soc., Chem. Commun., 1976, 743 DOI: 10.1039/C39760000743

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements