Issue 2, 1978

Detection of aromatic sulphinyl (ArSO·) radicals during the photolysis and thermolysis of S-aryl arenethiosulphonates and diaryl sulphoxides

Abstract

Evidence has been obtained using e.s.r. spectroscopy that arenesulphinyl radicals (ArSO·) are produced during the thermal and photolytic homolysis of both diaryl sulphoxides and S-aryl arenethiosulphonates, in the latter case via the initial production of the corresponding sulphonyl and thiyl radicals, ArSO2· and ArS·, respectively.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1978, 78-79

Detection of aromatic sulphinyl (ArSO·) radicals during the photolysis and thermolysis of S-aryl arenethiosulphonates and diaryl sulphoxides

B. C. Gilbert, B. Gill and M. D. Sexton, J. Chem. Soc., Chem. Commun., 1978, 78 DOI: 10.1039/C39780000078

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