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Modhephene (2), a new sesquiterpene representing the first naturally occurring carbocyclic [3.3.3]propellane, has been isolated from the toxic plant Isocoma Wrightii; its structure was confirmed by X-ray analysis of the corresponding diol (3).
L. H. Zalkow, R. N. Harris and D. Van Derveer, J. Chem. Soc., Chem. Commun., 1978, 420 DOI: 10.1039/C39780000420
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