Issue 12, 1978

Preparation and molecular structure of [Ta{H2Al(OC2H4OMe)2}(Me2PC2H4PMe2)2]2, a co-ordinatively unsaturated aluminohydride adduct of tantalum(I)

Abstract

Reaction of TaCl2(Me2PC2H4PMe2)2 with Na[H2Al(OC2H4OMe)2] affords [Ta{H2Al(OC2H4OMe)2}(Me2PC2H4PMe2)2]2, a co-ordinatively unsaturated complex based on an approximately square-pyramidal P4Ta–µ-H2–Al group.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1978, 500-501

Preparation and molecular structure of [Ta{H2Al(OC2H4OMe)2}(Me2PC2H4PMe2)2]2, a co-ordinatively unsaturated aluminohydride adduct of tantalum(I)

T. J. McNeese, S. S. Wreford and B. M. Foxman, J. Chem. Soc., Chem. Commun., 1978, 500 DOI: 10.1039/C39780000500

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