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An X-ray crystallographic study has shown that S5N6, prepared from Bu4N+S4N5– and bromine in methylene chloride, has a structure in which an –N![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
SN– unit bridges two sulphur atoms of an S4N4 cradle.
T. Chivers and J. Proctor, J. Chem. Soc., Chem. Commun., 1978, 642 DOI: 10.1039/C39780000642
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