The conversion of alcohols into alkyl chlorides and of acids into acid chlorides by aryl phosphines and carbon tetrachloride proceeds more rapidly when the phosphine is polymer-supported; in these reactions, the main pathway appears to involve two phosphorus-containing residues on the polymer reacting together.
C. R. Harrison and P. Hodge, J. Chem. Soc., Chem. Commun., 1978, 813 DOI: 10.1039/C39780000813
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