Issue 20, 1978

Direct displacement and coupling of prop-2-ynylic acetates with organocuprates

Abstract

The direct displacement of the acetate in 1-trimethylsilyl-3-acetoxyoct-1-yne (6) by the alkyl substituent of dialkylorganocuprates, and the lithium dimethylcuprate-medrated coupling of 3-acetoxy-1-trimethylsilylpent-4-en-1-yne (8b) are reported.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1978, 876-877

Direct displacement and coupling of prop-2-ynylic acetates with organocuprates

R. S. Brinkmeyer and T. L. Macdonald, J. Chem. Soc., Chem. Commun., 1978, 876 DOI: 10.1039/C39780000876

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