Issue 9, 1979
From the journal:

Journal of the Chemical Society, Chemical Communications

A new class of gold cluster compounds. Synthesis and X-ray structure of the octakis(triphenylphosphinegold) dializarinsulphonate, [Au8(PPh3)8](aliz)2

Mario Manassero,   Luciana Naldini  and  Mirella Sansoni  

Abstract

[Au9L8]3+(L = PPh3) reacts with L to give the new dication [Au8L8]2+; an X-ray analysis of [Au8(PPh3)8](aliz)2(aliz = alizarinsulphonate) shows that the central gold atom, while still displaying the usual short interactions with all the peripheral metal atoms, is no longer confined in an entirely metallic cage, but is also directly bonded to a phosphine ligand.

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Article information

DOI
https://doi.org/10.1039/C39790000385
Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 385-386

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A new class of gold cluster compounds. Synthesis and X-ray structure of the octakis(triphenylphosphinegold) dializarinsulphonate, [Au8(PPh3)8](aliz)2

M. Manassero, L. Naldini and M. Sansoni, J. Chem. Soc., Chem. Commun., 1979, 385 DOI: 10.1039/C39790000385

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