Issue 12, 1979

Chiral allenes are racemised by organocuprates

Abstract

The chiral allenes (1) and (2) are racemised in the presence of various organocuprates, or, in the case of the alcohol (2), by methylmagnesium iodide alone; the racemisations probably proceed via an anion radical.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 524-525

Chiral allenes are racemised by organocuprates

A. Claesson and L. Olsson, J. Chem. Soc., Chem. Commun., 1979, 524 DOI: 10.1039/C39790000524

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