Solid superacid catalyst was obtained by exposing H4TiO4 to 1 N H2SO4 and then calcining in air at 500 °C; this catalyst was active for skeletal isomerizations of butane and isobutane.
M. Hino and K. Arata, J. Chem. Soc., Chem. Commun., 1979, 1148 DOI: 10.1039/C39790001148
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