Issue 5, 1980

Electrosynthesis of alkyl and aryloxy titanium(III) complexes; electrochemical and spectroscopic characterization

Abstract

Electrochemical or chemical reduction of mono- or dicyclopentadienyl TiIV complexes gives the corrsponding radical anions which rearrange rapidly in both cases to the corresponding neutral monocyclopentadienyl TiIII complexes; by a combination of electrochemical and e.s.r. techniques, it was possible to understand the mechanism of reduction of these TiIV complexes.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 214-216

Electrosynthesis of alkyl and aryloxy titanium(III) complexes; electrochemical and spectroscopic characterization

A. Chaloyard, A. Dormond, J. Tirouflet and N. E. Murr, J. Chem. Soc., Chem. Commun., 1980, 214 DOI: 10.1039/C39800000214

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