Issue 6, 1980

Reaction of (PPh3)2ReH7 with dienes: preparation and some properties of trihydrido η4-diene and dihydro η5-dienyl complexes of rhenium

Abstract

The title compound reacts with dienes to give trihydrido η4-diene or dihydrido η5-dienyl complexes; pyrolysis of the η5-cyclohexadienyl compound (6) gives the hydrido arene complex (7), and protonation of the η4-diene compounds (4) leads to complete hydrogenation of the dienes.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 249-250

Reaction of (PPh3)2ReH7 with dienes: preparation and some properties of trihydrido η4-diene and dihydro η5-dienyl complexes of rhenium

D. Baudry and M. Ephritikhine, J. Chem. Soc., Chem. Commun., 1980, 249 DOI: 10.1039/C39800000249

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