The reaction of N2O with (η5-C5H5)2V gives (η5-C5H5)5 V5O6, whose structure, determined by X-ray crystallography, shows a trigonal bipyramid of five V atoms, each capped by a (η5-C5H5) ring, with oxygen atoms bridging each of the six faces of the trigonal bipyramid.
F. Bottomley and P. S. White, J. Chem. Soc., Chem. Commun., 1981, 28 DOI: 10.1039/C39810000028
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