Issue 5, 1981
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and X-ray structural characterization of the centred icosahedral gold cluster compound [Aul3(PMe2Ph)10Cl2](PF6)3; the realization of a theoretical prediction

Clive E. Briant,   Brian R. C. Theobald,   James W. White,   Linda K. Bell,   D. Michael P. Mingos  and  Alan J. Welch  

Abstract

The gold(I) complexes AuCl(PR3)(PR3= PPh3, PMePh2, and PMe2Ph) react with Ti(η-C7H8)2 to form a variety of cationic gold cluster complexes; single-crystal X-ray analysis of one of these, [Au13-(PMe2Ph)10Cl2](PF6)3, has confirmed a centred icosahedral geometry for the cluster, in agreement with an earlier theoretical prediction.

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Article information

DOI
https://doi.org/10.1039/C39810000201
Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 201-202

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Synthesis and X-ray structural characterization of the centred icosahedral gold cluster compound [Aul3(PMe2Ph)10Cl2](PF6)3; the realization of a theoretical prediction

C. E. Briant, B. R. C. Theobald, J. W. White, L. K. Bell, D. M. P. Mingos and A. J. Welch, J. Chem. Soc., Chem. Commun., 1981, 201 DOI: 10.1039/C39810000201

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