Issue 5, 1981
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and X-ray characterization of an iodine-bridged tetranuclear gold cluster, di-µ-iodo-tetrakis(triphenylphosphine)-tetrahedro-tetragold

Francesco Demartin,   Mario Manassero,   Luciana Naldini,   Ruggero Ruggeri  and  Mirella Sansoni  

Abstract

The reaction of[Au9(PPh3)8][NO3]3with KI in acetone yields [Au4(µ-I)2(PPh3)4] which has been shown by X-ray crystallography to contain a tetrahedral gold cluster connected to four terminal triphenylphosphine groups and two edge-bridging iodine ligands; the latter bonding mode is novel for gold clusters.

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Article information

DOI
https://doi.org/10.1039/C39810000222
Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 222-223

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Synthesis and X-ray characterization of an iodine-bridged tetranuclear gold cluster, di-µ-iodo-tetrakis(triphenylphosphine)-tetrahedro-tetragold

F. Demartin, M. Manassero, L. Naldini, R. Ruggeri and M. Sansoni, J. Chem. Soc., Chem. Commun., 1981, 222 DOI: 10.1039/C39810000222

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