Photochemistry of [(η-C5H5)2ReH] and [(η-C5H5)(η2-C5H6)Re(CO)2] in low temperature matrices: hydrogen loss and hydrogen migration
Abstract
On photolysis of[(η-C5H5)2ReH](1) in Ar/CO matrices [(η-C5H5)2Re], HCO, and a monocarbonyl are generated; photolysis of [(η-C5H5)(η2-C5H6)Re(CO)2]in Ar matrices produces three carbonyl intermediates followed by (1).