SCHEDULED MAINTENANCE
Hydromagnesiation of prop-2-ynylic alcohols proceeds with stereo- and regio-specificity, affording, under mild conditions, the alkenylmagnesium halides (5) in almost quantitative yields, thus providing a novel and simple route to terpenoids.
F. Sato, H. Ishikawa, H. Watanabe, T. Miyake and M. Sato, J. Chem. Soc., Chem. Commun., 1981, 718 DOI: 10.1039/C39810000718
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