The general problem of the synthesis of compounds containing chiral methyl groups adjacent to an asymmetric center is addressed for the specific case of valine having such groups exclusively at the 3pro(R) position.
C. A. Townsend, A. S. Neese and A. B. Theis, J. Chem. Soc., Chem. Commun., 1982, 116 DOI: 10.1039/C39820000116
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