Issue 8, 1982

Cluster chemistry. Reactions between metal carbonyl clusters and Lewis bases initiated by radical ions: improved syntheses of substituted derivatives of M3and M4 clusters(M = Fe, Ru, Os or Co)

Abstract

Addition of catalytic amounts of Ph2Co˙to a mixture of the appropriate cluster with stoicheiometric amounts of Lewis base in tetrahydrofuran gave the substituted derivatives [Fe3(CO)11(L)],[Ru3(CO)12–n(L)n],[Os3(CO)11(L)], and [H4Ru4(CO)12–n(L)n][n= 1–3; L = ButNC,PR3,P(OR)3]in greatly improved yields.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 442-444

Cluster chemistry. Reactions between metal carbonyl clusters and Lewis bases initiated by radical ions: improved syntheses of substituted derivatives of M3and M4 clusters(M = Fe, Ru, Os or Co)

M. L. Bruce, D. C. Kehoe, J. G. Matisons, B. K. Nicholson, P. H. Rieger and M. L. Williams, J. Chem. Soc., Chem. Commun., 1982, 442 DOI: 10.1039/C39820000442

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