Issue 12, 1982

Phototochemistry of cation radicals in solution; photoinduced electron-transfer reactions between alcholos and the N,N,N′,N′,-tetraphenyl-p-phenylenediamine cation radical

Abstract

Irradiation of the N,N,N′,N′-tetraphenyl-p-phenylanediamine cation radical (TPPD·+) with benzyl alchohol causes its reduction to TPPD and oxidation of the alcohol into benzaldehyde; with benzhydrol and 1-phenylethanol the corresponding symmetrical ethers are formed in a photocatalytic process in which TPPD·+ is recycled via two successive electron transfers.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 654-655

Phototochemistry of cation radicals in solution; photoinduced electron-transfer reactions between alcholos and the N,N,N′,N′,-tetraphenyl-p-phenylenediamine cation radical

J. Moutet and G. Reverdy, J. Chem. Soc., Chem. Commun., 1982, 654 DOI: 10.1039/C39820000654

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