SCHEDULED MAINTENANCE
The reaction of Co(BF4)2·6H2O with tetraphosphorus trisulphide in the presense of triphose [triphose = 1,1,1-tris (diphenylphosphinomethyl)ethane] yields [(triphose)CoP2 S]BF4, which has been shown by a single-crystal X-ray study to contain the triangular diphosphorus–sulphur unit linked to the metal as a trihapto-ligands.
M. Di Vaira, M. Peruzzini and P. Stoppioni, J. Chem. Soc., Chem. Commun., 1982, 894 DOI: 10.1039/C39820000894
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