La(fod)3(fod = 6,6,7,7,8,8,8-heptafluoro-2,2-dimethyloctane-3,5-dionato) diamagnetic complexation shifts can be used as a sensitive probe of the extent and pattern of π-electron delocalisation in aromatic and olefinic aldehydes and ketones and hence as a tool for the assignment of 13C-n.m.r. signals in complex, unsaturated molecules.
R. J. Abraham, H. A. Bergen, D. J. Chadwick and F. Sancassan, J. Chem. Soc., Chem. Commun., 1982, 998 DOI: 10.1039/C39820000998
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