Se2I4(Sb2F11)2 has been prepared and its structure determined by single crystal X-ray diffraction; the Se2I42+cation has an eclipsed S2O42– type structure with two Sel2+ units joined by a weak selenium–selenium bond [2.841(2)Å] and very weak iodine–iodine interactions [3.756(2), 3.661(2)Å].
W. A. S. Nandana, J. Passmore, P. S. White and C. Wong, J. Chem. Soc., Chem. Commun., 1982, 1098 DOI: 10.1039/C39820001098
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