Sulphur dioxide adds in acheleotropic way to norbornadiene giving 4-thiatetracyclo[3.3.0.0.2,8.03,6]octane 4,4-dioxide, while non-cycloaddition products are obtained with other homo-conjugated dienes.
O. De Lucchi and V. Lucchini, J. Chem. Soc., Chem. Commun., 1982, 1105 DOI: 10.1039/C39820001105
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