In accordance with predictions based on molecular orbital calculations, the crystal structure of 2,2′-dilithiobiphenyl consists of monomeric units units containing a planar biphenyl unit symmetrically bridged by two tweda-complexed lithium atoms (tmeda = Me2NCH2CH2NMe2).
U. Schubert, W. Neugebauer and P. von Ragué Schleyer, J. Chem. Soc., Chem. Commun., 1982, 1184 DOI: 10.1039/C39820001184
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