Issue 22, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

(Dimethyl)[tris(trimethylsilyl)methyl]silyl cyanate and related species: the first silicon cyanates

Colin Eaborn,   Paul D. Lickiss,   Germania Marquina-Chidsey  and  Esther Y. Thorli  

Abstract

Treatment of (Me3Si)3CSiMe2l, (Me3Si)3 CSiMe(OMe)l, or (Me3Si)3CSiPh2l with AgOCn in CH2Cl2has given (Me3Si)3 CSiMe2(OCN),(Me3Si)3CSiMe(OMe)(OCN), and (Me3Si)2C(SiPh2Me)[SiMe2(OCN)], respectively, the first normal cyanates of silicon; on heating these isomerize to the corresponding isocyanates.

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Article information

DOI
https://doi.org/10.1039/C3982001326A
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 1326a-1326a

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(Dimethyl)[tris(trimethylsilyl)methyl]silyl cyanate and related species: the first silicon cyanates

C. Eaborn, P. D. Lickiss, G. Marquina-Chidsey and E. Y. Thorli, J. Chem. Soc., Chem. Commun., 1982, 1326a DOI: 10.1039/C3982001326A

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