Issue 3, 1983

Mechanism for initial carbene formation in olefin metathesis over fixed Mo catalysts

Abstract

It is indicated that the initial carbene for ethene or propene metathesis over active fixed Mo catalysts with well defined reaction sites is formed by a 1,2-hydrogen shift via a molybdenum–n-alkenyl intermediate.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 130-132

Mechanism for initial carbene formation in olefin metathesis over fixed Mo catalysts

Y. Iwasawa and H. Hamamura, J. Chem. Soc., Chem. Commun., 1983, 130 DOI: 10.1039/C39830000130

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