Issue 6, 1983
From the journal:

Journal of the Chemical Society, Chemical Communications

Mono-oxigenase-like dioxygen activation leading to alkane hydroxylation and olefin epoxidation by an MnIII(porphyrin)–ascorbate biphasic system

Daniel Mansuy,   Marc Fontecave  and  Jean-François Bartoli  

Abstract

A biphasic H2O–C6H6 system, which has MnIII(tetraphenylporphyrin)(Cl) and a phase transfer agent as catalysts and ascorbate as a reducing agent, activates dioxygen leading to selective epoxidation of olefins and hydroxylation of alkanes under mild conditions.

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Article information

DOI
https://doi.org/10.1039/C39830000253
Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 253-254

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Mono-oxigenase-like dioxygen activation leading to alkane hydroxylation and olefin epoxidation by an MnIII(porphyrin)–ascorbate biphasic system

D. Mansuy, M. Fontecave and J. Bartoli, J. Chem. Soc., Chem. Commun., 1983, 253 DOI: 10.1039/C39830000253

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