Issue 12, 1984

Mechanistic and synthetic aspects of intramolecular alkoxide–allene cyclizations

Abstract

Intramolecular cyclization of the methoxyallene–alkoxide adducts (1a) proceeds along two different pathways via a methoxyallyl radical to give either a dihydrofuran, or vinyl epoxide, depending upon the steric environment of the redical anion.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 804-806

Mechanistic and synthetic aspects of intramolecular alkoxide–allene cyclizations

P. Magnus and P. Albaugh-Robertson, J. Chem. Soc., Chem. Commun., 1984, 804 DOI: 10.1039/C39840000804

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