SCHEDULED MAINTENANCE
The product of the reaction between AgI and tris(trimethylsilyl)methyl-lithium in tetrahydrofuran (thf) has been shown by X-ray diffraction to be the ionic ate complex [Li(thf)4][Ag{C(SiMe3)3}2]; evidence is presented that this and the analogous ate complexes of lithium and copper retain their structures in solution.
C. Eaborn, P. B. Hitchcock, J. D. Smith and A. C. Sullivan, J. Chem. Soc., Chem. Commun., 1984, 870 DOI: 10.1039/C39840000870
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