Issue 19, 1984

Chelation-controlled regioselective epoxide–carbonyl rearrangement: a ring enlargement route to (±)-modhephene

Abstract

A new formal total synthesis of (±)-modhephene (1) employing a chelation-controlled regioselective epoxide-carbonyl rearrangement as the key step is described.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1259-1260

Chelation-controlled regioselective epoxide–carbonyl rearrangement: a ring enlargement route to (±)-modhephene

Y. Tobe, S. Yamashita, T. Yamashita, K. Kakiuchi and Y. Odaira, J. Chem. Soc., Chem. Commun., 1984, 1259 DOI: 10.1039/C39840001259

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