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6α(7α)-(Methylthio)penicillins and cephalosporins have been converted into novel antibacterially active 6α(7α)-formamido derivatives by using either mercury(II) acetate and ammonia followed by formylation, or mercury(II) acetate and N,N-bis(trimethylsilyl) formamide in a single step.
P. H. Milner, A. W. Guest, F. P. Harrington, R. J. Ponsford, T. C. Smale and A. V. Stachulski, J. Chem. Soc., Chem. Commun., 1984, 1335 DOI: 10.1039/C39840001335
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