SCHEDULED MAINTENANCE
An efficient synthesis of the ansa chain of rifamycin-S corresponding to the C-21 to C-27 segment is described, starting from a bicyclic precursor endo,endo-2,4-dimethyl-8-oxabicyclo[3.2.1]oct-6-en-3-one.
A. V. R. Rao, J. S. Yadav and V. Vidyasagar, J. Chem. Soc., Chem. Commun., 1985, 55 DOI: 10.1039/C39850000055
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