Issue 11, 1985
From the journal:

Journal of the Chemical Society, Chemical Communications

Hydrolytic cleavage of the Cr–Cr triple bond in (C5Me5)2Cr2(CO)4. The formation and crystal structure of [(C5Me5)4Cr4(µ-OH)6](BF4)2, an adamantane analogue

D. Wormsbächer,   K. M. Nicholas  and  A. L. Rheingold  

Abstract

(C5Me5)2Cr2(CO)4(Cr[triple bond, length half m-dash]Cr) reacts with moist LiPF6 in CH2Cl2 at room temperature, or with H2O directly in refluxing toluene, to produce the mononuclear hydride (C5Me5)Cr(CO)3H; the latter reaction also produces a salt [(C5Me5)4Cr4(µ-OH)6][(C5Me5)Cr(CO)3]2 whose BF4– derivative, [(C5Me5)4Cr4(µ-OH)6](BF4)2, has been characterized by X-ray crystallography.

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Article information

DOI
https://doi.org/10.1039/C39850000721
Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 721-722

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Hydrolytic cleavage of the Cr–Cr triple bond in (C5Me5)2Cr2(CO)4. The formation and crystal structure of [(C5Me5)4Cr4(µ-OH)6](BF4)2, an adamantane analogue

D. Wormsbächer, K. M. Nicholas and A. L. Rheingold, J. Chem. Soc., Chem. Commun., 1985, 721 DOI: 10.1039/C39850000721

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