SCHEDULED MAINTENANCE
Sirohydrochlorin is an isobacterichlorin isolated (a) as the metal-free prosthetic group of sulphite reductase and (b) as the aromatised form of the di-C-methylated intermediate on the biosynthetic pathway to vitamin B12; the synthesis is described of the natural enantiomer of sirohydrochlorin and also of its octamethyl ester using a mild photochemical route.
M. H. Block, S. C. Zimmerman, G. B. Henderson, S. P. D. Turner, S. W. Westwood, F. J. Leeper and A. R. Battersby, J. Chem. Soc., Chem. Commun., 1985, 1061 DOI: 10.1039/C39850001061
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