The first perfluoro crown ethers, perfluoro 18-crown-6, perfluoro 15-crown, and perfluoro 12-crown-4, have been prepared by carefully controlled elemental fluorination; although they are weaker bases than their parent compounds, perfluoro crown ethers are materials which will have a number of applications.
W. Lin, W. I. Bailey and R. J. Lagow, J. Chem. Soc., Chem. Commun., 1985, 1350 DOI: 10.1039/C39850001350
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