SCHEDULED MAINTENANCE
For M = K, M[HRu3(CO)9(dppe)] reacts with trans-[Ru(CO)2(P–P)2][SbF6]2[P–P = 1,2-dis(diphenylpgosphino)ethane(dppe)or 1,2-dis(diphenylphosphino)benzene(dp)] to give trins-[Ru(CHO)(CO)(P–P)2]+ whereas for M = Na, no reaction is observed; the extent of ion-pairing is shown to be responsible for this difference is reactivity.
D. S. Barratt and D. J. Cole-Hamilton, J. Chem. Soc., Chem. Commun., 1985, 1559 DOI: 10.1039/C39850001559
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