Novel polyselenides and polytellurides have been prepared by means of the stabilizing tris(trimetylsilyl)methyl group; [(Me3Si)3C]2Te3, the first compound containing a three tellurium atom chain, crystallizes as a trans-rotamer with a bonding angle of 103.8(1)° at the central tellurium atom and Te–Te bond distances of 2,710(1)Å.
F. Sladky, B. Bildstein, C. Rieker, A. Gieren, H. Betz and T. Hübner, J. Chem. Soc., Chem. Commun., 1985, 1800 DOI: 10.1039/C39850001800
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