Issue 2, 1986

The preparation and isolation of 5-methyl-1,3,2,4-dithiadiazolyl and the facile rearrangement of the 1,3,2,4-dithiadiazolyl radicals to the disulphide isomers, 2,3,1,4-dithiadiazolyl

Abstract

The radical 5-methyl-1,3,2,4-dithiadiazolyl has been prepared and isolated, and it and two new derivatives undergo essentially quantitative isomerisation to 2,3,1,4-dithiadiazolyl at room temperature; the rate of isomerisation follows second order kinetics and the mechanism is postulated to involve an unstable π*–π* dimer intermediate.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 140-142

The preparation and isolation of 5-methyl-1,3,2,4-dithiadiazolyl and the facile rearrangement of the 1,3,2,4-dithiadiazolyl radicals to the disulphide isomers, 2,3,1,4-dithiadiazolyl

N. Burford, J. Passmore and M. J. Schriver, J. Chem. Soc., Chem. Commun., 1986, 140 DOI: 10.1039/C39860000140

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