Issue 8, 1986

Preparation and structure of the first complex of an early transition metal and a calixarene, calix[6]arene[TiCl2(µ-O)TiCl3]2

Abstract

Hexamethoxycalix[6]arene reacts with TiCl4 to give a macrocycle to which two bimetallic units, (Cl3TiOTiCl2), have been attached; the X-ray crystal structure shows that the metal complex has broken an O–Me bond, linking one Ti atom to the calixarene through a full Ti–O bond and two TiOMe donor bonds, while the other Ti atom remains co-ordinatively unsaturated.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 610-611

Preparation and structure of the first complex of an early transition metal and a calixarene, calix[6]arene[TiCl2(µ-O)TiCl3]2

S. G. Bott, A. W. Coleman and J. L. Atwood, J. Chem. Soc., Chem. Commun., 1986, 610 DOI: 10.1039/C39860000610

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