The reaction of carbon dioxide, diethylamine, and hex-1-yne(1a) or phenylacetylene (1b), catalysed by Ru3(CO)12, gave the vinyl carbamates (2a), (3a) and (4a) or (2b) and (3b).
Y. Sasaki and P. H. Dixneuf, J. Chem. Soc., Chem. Commun., 1986, 790 DOI: 10.1039/C39860000790
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