Reaction of the substituted diazomethane with the acidic and conjugate base forms of the zeolite ZSM-5 is used to model carbon–carbon bond formation for methanol conversion into hydrocarbons, and the results re-inforce the involvement of a surface bonded C1 intermediate rather than a non-bonded trimethyloxonium ion ylide.
R. Hunter and G. J. Hutchings, J. Chem. Soc., Chem. Commun., 1986, 1006 DOI: 10.1039/C39860001006
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