Issue 15, 1986

Differentiation of bacteriochlorin and isobacteriochlorin formation by metallation. High yield synthesis of porphyrindiones via OsO4 oxidation

Abstract

Zinc oxochlorins (porphyrinones) react with osmium tetroxide to give exclusively adjacent-ring saturated isobacteriochlorins without any bacteriochlorins that would normally arise from such a reaction with free base porphyrinones; the diols can be converted into the baem d1-like porphyrindiones.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1213-1215

Differentiation of bacteriochlorin and isobacteriochlorin formation by metallation. High yield synthesis of porphyrindiones via OsO4 oxidation

C. K. Chang, C. Sotitiou and W. Wu, J. Chem. Soc., Chem. Commun., 1986, 1213 DOI: 10.1039/C39860001213

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