Issue 21, 1986

In situ Fourier transform i.r. observation of methylating species in ZSM-5

Abstract

In situ Fourier transform i.r. spectra show that MeOH in ZSM-5 forms an AlOMe species above 473 K which correlates with the onset of hydrocarbon formation and which methylates benzene, ethene, propene, and cyclopentene; MeOMe is protonated by internal acid sites at low temperatures but forms the same methylating species at 473 K and above.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1611-1613

In situ Fourier transform i.r. observation of methylating species in ZSM-5

T. R. Forester, S. Wong and R. F. Howe, J. Chem. Soc., Chem. Commun., 1986, 1611 DOI: 10.1039/C39860001611

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