Issue 23, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Photochemical activation of ethene C–H bonds of (η5-C5H5)lr(C2H4)2 in low-temperature matrices and in solution

David M. Haddleton  and  Robin N. Perutz  

Abstract

A series of vinyl hydride complexes, cplr(L)(η1-C2H3)H (cp =η5-C5H5), have been characterised on photolysis of cplr(C2H4)2 by i.r. spectroscopy in low-temperature matrices (L = C2H4, CO) and by n.m.r. spectroscopy in solution (L = C2H4, PPh3, Me2SO); cplr(C2H4)(η1-C2H3)H undergoes secondary photolysis in matrices to form the vinylidene complex, cplr(C[double bond, length half m-dash]CH2)(H)2.

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Article information

DOI
https://doi.org/10.1039/C39860001734
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1734-1736

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Photochemical activation of ethene C–H bonds of (η5-C5H5)lr(C2H4)2 in low-temperature matrices and in solution

D. M. Haddleton and R. N. Perutz, J. Chem. Soc., Chem. Commun., 1986, 1734 DOI: 10.1039/C39860001734

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