Neutron diffraction shows that the title compound contains both N–H ⋯ Cl and N–H ⋯ Pt bonds in the solid; such hydrogen bonding is considered to be responsible for the high solubility in dichloromethane of this and related adducts involving cis-[PtX2L2](X = Cl or Br, L = NH2Me or NHMe2) complexes which are otherwise practically insoluble.
L. Brammer, J. M. Charnock, P. L. Goggin, R. J. Goodfellow, T. F. Koetzle and A. G. Orpen, J. Chem. Soc., Chem. Commun., 1987, 443 DOI: 10.1039/C39870000443
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