Issue 7, 1987

Hydrocupration of alkynes: a simple synthesis of (E,E)-1,3-dienes

Abstract

Copper(I) hydride species, prepared in situ in tetrahydrofuran using NaBH4–MgBr2–Et3N–CuCl or NaH–MgBr2–CuCl reagent systems, convert terminal alkynes into (E,E)-1,3-dienes in good yields.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 495-496

Hydrocupration of alkynes: a simple synthesis of (E,E)-1,3-dienes

S. A. Rao and M. Periasamy, J. Chem. Soc., Chem. Commun., 1987, 495 DOI: 10.1039/C39870000495

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