Issue 11, 1987

A dual regiocontrol in the copper-catalysed Grignard reaction with primary allylic acetates

Abstract

The reaction of primary allylic acetates with Grignard reagents in the presence of catalytic amounts of Li2CuCl4 can be regiochemically controlled to give either α- or γ-substitution of the allylic acetoxy group.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 827-829

A dual regiocontrol in the copper-catalysed Grignard reaction with primary allylic acetates

Jan-E. Bäckvall and M. Sellén, J. Chem. Soc., Chem. Commun., 1987, 827 DOI: 10.1039/C39870000827

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